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21.
Lianfeng Zhao Kwangdong Roh Sara Kacmoli Khaled Al Kurdi Samik Jhulki Stephen Barlow Seth R. Marder Claire Gmachl Barry P. Rand 《Advanced materials (Deerfield Beach, Fla.)》2020,32(25):2000752
The performance of lead-halide perovskite light-emitting diodes (LEDs) has increased rapidly in recent years. However, most reports feature devices operated at relatively small current densities (<500 mA cm−2) with moderate radiance (<400 W sr−1 m−2). Here, Joule heating and inefficient thermal dissipation are shown to be major obstacles toward high radiance and long lifetime. Several thermal management strategies are proposed in this work, such as doping charge-transport layers, optimizing device geometry, and attaching heat spreaders and sinks. Combining these strategies, high-performance perovskite LEDs are demonstrated with maximum radiance of 2555 W sr−1 m−2, peak external quantum efficiency (EQE) of 17%, considerably reduced EQE roll-off (EQE > 10% to current densities as high as 2000 mA cm−2), and tenfold increase in operational lifetime (when driven at 100 mA cm−2). Furthermore, with proper thermal management, a maximum current density of 2.5 kA cm−2 and an EQE of ≈1% at 1 kA cm−2 are shown using electrical pulses, which represents an important milestone toward electrically driven perovskite lasers. 相似文献
22.
《Current Opinion in Solid State & Materials Science》2019,23(4):100764
Extensive research has been directed towards the reinvention of paper for advanced applications. Nanocellulose-based films, a novel class of specialty paper primarily made of nanocellulose, demonstrate an ideal combination of sustainability and enhanced or novel properties. Enormous efforts have been devoted to enhancing these intrinsic properties and/or creating novel functions to expedite and expand the use of these materials in high-end fields such as touchscreen, solar cells, and nanogenerators. We review state-of-the-art advances in nanocellulose-based films and their utilization in several emerging and promising fields. We begin with an introduction of four types of nanocellulose-based films distinguished by their functional material loads (e.g., synthetic macromolecular polymers, 0D, 1D, and 2D nanomaterials), which involves their manufacturing techniques, structure design, properties, novel functions, and underlying principles. Additionally, we summarize the value-added applications of nanocellulose-based films in flexible electronics, energy converting or harvesting devices, and water treatment. Finally, we provide a critical viewpoint on the remaining challenges and future opportunities in this field. 相似文献
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To solve the problem of complex,cumbersome and error-prone configuration of security devices caused by the heterogeneous configuration modes in complex networks,a dynamic template-based scheme for translating and configuring policy was proposed.In detail,considering the code’s features,the code-based template for translating policies was constructed to configure the command line conversion,and the keyword comparison method was used to ensure the accuracy of policy configuration.Experiments show that the scalability and the accuracy of the proposed scheme. 相似文献
24.
ABSTRACTIn this paper, an electromagnetic torque device based on the theoretical model was established to determine the optimum frequency accurately and conveniently in billet and bloom continuous casting with in-mould electromagnetic stirring (M-EMS). Magnetic characteristics with M-EMS was investigated by numerical simulation and physical experiment with the application of electromagnetic torque device and gauss meter. In addition, the effects of stirring frequency with M-EMS on macro segregation and equiaxed crystal ratio were compared and analysed for 55SiCr with 150?mm?×?150?mm billet caster and BU with 310?×?360?mm bloom caster by a series of plant trials, respectively. The results showed that maximum magnetic flux density and maximum electromagnetic torque occurred with different frequency and same current in M-EMS, and central equiaxed crystal ratio and macro segregation has been significantly improved by optimum frequency with M-EMS. 相似文献
25.
《Ceramics International》2022,48(5):6157-6165
Electrochemical system centered on hierarchically carbon-based metal sulphide assemblies are of great fame for competent supercapacitors. Herein, the synthesis of a hierarchical CNT anchored MoS2–Bi2S3 nanocomposite is reported. Attractively, a vertically grown Bi2S3 nanorods supported on MoS2 nanosheets with carbon framework acts as a highly effective electrode in alkaline electrolyte. More interestingly, this hierarchical structure and synergetic upshot of CNT and composites provide excess coverage of active sites with improved conductivity and stability. Advancing from the physical and compositional properties of nanocomposites, the specific capacitance of MoS2–Bi2S3@CNT composites is measured to be 1338 F/g at 10 mV/s, columbic efficiency of 99.5% over 10000 cycles and long-term stability (60% retention at 0.5 A g?1 over 2000 cycles and 34.6% up to 10000 cycles). The success of this MoS2–Bi2S3@CNT composite may be attributed to the structural advantages, admirable cyclic stability, and better capacitance retention for supercapacitor applications. 相似文献
26.
《International Journal of Hydrogen Energy》2021,46(77):38416-38424
Marigold flower (MG; Tagetes erecta) derived Graphene quantum dots (GQDs) have been successfully reported for the fabrication of supercapacitor electrodes in charge storage devices. The GQDs have been synthesized through a hydrothermal route using biomass viz. Waste material (MG) without adding any hazardous chemicals. The successful formation of GQDs as elaborated has been confirmed by various analytical characterization techniques. The as-synthesized GQDs have been electrodeposited on the Ni foil (working electrode) with the help of PVDF (binder) and subsequently, cyclic voltammetry (CV) has been conducted to access specific capacitance, energy density, and other parameters. Moreover, the galvanometric charge/discharge (GCD) technique has been employed due to its accuracy and reliability. Maximum areal specific capacitance has been found as 1.6008 F/cm2 with the current density of 2.0 A/g even after loading a little amount of material on the electrode. The high magnitude of columbic efficiency (160.08), energy density (17.78 Wh/kg), and specific capacitance of 200 F/g at current density 2.0 A/g within a voltage range of −0.55 V to +0.25 V in 2 M KOH electrolyte solution indicate a good electrocapacitive performance of the as-synthesized material. Moreover, the as-synthesized GQDs have shown excellent capacitive retention after 1000th cycles which clearly embarks its sustainable electrocapacitive nature and henceforth offers outstanding potential for the applications in energy storage devices like supercapacitors. 相似文献
27.
为了解决在裂隙溶洞岩体条件下,散装炸药由于良好的流动性,容易发生炸药泄漏,形成安全隐患并影响爆破效果的问题。结合具有典型喀斯特地貌特征的贵阳龙洞堡机场三期扩建工程中露天爆破施工的实际情况,以检测数据为基础,提出了一种适用于不良地质条件的散装炸药施工新方法。设计前,对爆区采用地质雷达进行地质检测,探测地下溶洞等不良构造,基于探测数据有针对性的进行爆破设计;使用孔内摄像技术对炮孔内部条件进行检测,从而确定可能发生炸药泄漏的位置。在施工过程中,采用分段装药、包装炸药隔离、高强度聚乙烯膜柔性隔离等技术控制炸药泄漏。在龙洞堡机场扩建工程的露天爆破中应用结果表明,合理运用该技术,可以有效避免混装炸药因泄漏而流失,从而改善裂隙岩体条件的爆破效果。 相似文献
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